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Modeling Study on the Impact of Climate Change on Air Pollution
WU Yazhen, LI Danyang, ZHANG Lin, DAI Hancheng
Acta Scientiarum Naturalium Universitatis Pekinensis    2023, 59 (5): 854-870.   DOI: 10.13209/j.0479-8023.2023.010
Abstract256)   HTML    PDF(pc) (2267KB)(211)       Save
Evaluating the schemes and characteristics of models that are applied in studying the mechanism of how climate change would impact air pollution is key to providing a better understanding of the current studies and supporting modeling research in the future. This study reviews existing modeling studies on the topic “climate change impact on air pollution” based on literature investigation. Three types of modeling studies at different spatial scales – global and regional – are identified, and the characteristics and applicability of different research methods are compared. Furthermore, using data from the CMIP5 climate model intercomparison project and the atmospheric chemical transport model WRF-Chem, the impacts of future changes in meteorology and pollutant emissions in the context of climate change on near-surface summertime O3 concentration in China in 2050 are studied, with the Beijing-Tianjin-Hebei region, Yangtze River Delta region, and Pearl River Delta region selected as representatives for analysis. Results show that under the RCP8.5 climate change and emission pathway, both meteorological and emission changes will impose significant effects on summer ozone concentrations in China by the middle of this century. In most regions of China, changes in emissions would have a significant influence on ozone concentration, but the meteorological field near the East China Sea would also significantly affect future ozone pollution. In addition, a certain degree of interaction between the two factors exists.
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Reinforcement Learning of Spiking Neural Network Based on Knowledge Distillation
ZHANG Ling, CAO Jian, ZHANG Yuan, FENG Shuo, WANG Yuan
Acta Scientiarum Naturalium Universitatis Pekinensis    2023, 59 (5): 757-763.   DOI: 10.13209/j.0479-8023.2023.065
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We propose the reinforcement learning method of Spike Distillation Network (SDN), which uses STBP gradient descent method to realize the knowledge distillation from Deep Neural Network (DNN) to Spiking Neural Network (SNN) reinforcement learning tasks. Experiment results show that SDN converges faster than traditional SNN reinforcement learning and DNN reinforcement learning methods, and can obtain a SNN reinforcement learning model with smaller parameters than DNN. SDN is deployed to the neuromorphology chip, and the power consumption is lower than DNN, proving that SDN is a new and high-performance SNN reinforcement learning method and can accelerate the convergence of SNN reinforcement learning.
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Multi-turn Event Argument Extraction Based on Role Information Guidance
YU Yuanfang, ZHANG Yong, ZUO Haoyang, ZHANG Lianfa, WANG Tingting
Acta Scientiarum Naturalium Universitatis Pekinensis    2023, 59 (1): 83-91.   DOI: 10.13209/j.0479-8023.2022.064
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Aiming at the two problems of insufficient utilization of role information and lack of interaction between arguments in general domain event argument extraction research, a role information-oriented multi-turn event argument extraction model is proposed to enhance the semantic information of texts and interactions between arguments. The interactive capability can improve the performance of event argument extraction. First, to better utilize role knowledge to guide argument extraction, the model builds role knowledge based on role definitions, independently encodes role information and text, and uses a method based on attention mechanism to obtain label-knowledge-enhanced representations. Then the augmented embeddings are used to predict whether or not each token is a start or end position for some category. At the same time, in order to make full use of the interaction between event arguments in the extraction process, inspired by the multi-turn dialogue model, this paper designs a multi-turn event argument extraction algorithm. The algorithm refers to the natural logic of “easiness to hardness”, and selects the character with the highest prediction probability, that is, the most predictable character, for extraction each time. In the process of argument extraction, in order to model the interaction between arguments, the model introduces historical embedding, and updates the historical embedding after each prediction to help the extraction of the next round of event arguments. The experimental results show that the guidance of role information and multi round extraction algorithm effectively improve the performance of argument extraction, and the method achieves state-of-the-art performance.
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Effects of Carbon-to-Nitrogen Ratio on Nitrogen and Phosphate Removal in A/O-MBR Wastewater Treatment Process
TAO Huchun, TONG Hao, WANG Jian, HUANG Yilong, ZHANG Lijuan, YANG Kai, DING Lingyun, QIAO Xuejiao, DOU Min, XU Nan
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (4): 680-686.   DOI: 10.13209/j.0479-8023.2022.037
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The changing profiles of NH4+-N, total nitrogen (TN) and total phosphate (TP) were investigated in the A/O-MBR process at high and low carbon-to-nitrogen ratios. By elevating the carbon-to-nitrogen ratio, there was an increase in the removal efficiency of TN from 44.1%±8.9% to 78.5%±7.9%, while the removal efficiency remained unchanged for TP. Metabolite analyses revealed that enhanced metabolism of amino acids contributed significantly to efficient nitrogen removal from wastewater and the up-regulation of riboflavin biosynthesis, further improving the water quality.
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A Study on the Electro-and-bioelectro-deposition of Heavy Metals in Municipal Solid Waste Incinerator Fly Ash
FENG Zhendong, LEI Tao, ZHANG Shanfa, ZHANG Lijuan, DING Lingyun, TAO Huchun
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (4): 673-679.   DOI: 10.13209/j.0479-8023.2022.034
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The contents and leaching concentrations of heavy metals from municipal solid waste incinerator (MSWI) fly ash were investigated in Shenzhen. Targeting at Cu, Pb and Zn as the key heavy metals, aqueous solutions containing Cu(II), Pb(II) and Zn(II) of 100 mg/L, 200 mg/L and 300 mg/L were synthesized to test the feasibility and efficiency of electro-and-bioelectro-deposition of heavy metals. In a bio-electrochemical system (BES), the removal and recovery efficiency of Cu(II) was >98%. In the subsequent electro-deposition reactor (ER), the concentrations of Pb(II) and Zn(II) were decreased from 200 and 300 mg/L to 23.5±1.1 and 4.3±0.2 mg/L with external voltage of 1.5 and 2.5 V, respectively. Energy consumption analysis revealed that extra electricity of 16.55 kWh was generated by 1 kg Cu(II) reduction in BES, while electricity of 60.91 kWh and 114.27 kWh were consumed by 1 kg Pb(II) and Zn(II) treatment in ER, and the heavy metal ions were reducted to free elements, oxides and salts. These results suggest that a combined BES and ER technology has advantages in metal recovery and energy saving. 
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Metabolic Influence of Mercury Contamination on Bacterial Mercury Methylation by Geobacter sulfurreducens PCA
TAO Huchun, QIAN Lu, ZHANG Lijuan, DING Lingyun, FANG Fang, DAI Maifan, WEI Ruqian
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (3): 526-536.   DOI: 10.13209/j.0479-8023.2022.036
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Metabolomics, a rising omics approach, was employed to screen out cellular significantly differential metabolites and analyze related metabolic pathways in bacterial Hg-methylating process. Under the stress of Hg(II) at environmentally relevant concentrations (0?100 μg/L), the adsorbed/assimilated Hg(II) was utilized by Hg-methylator of Geobacter sulfurreducens PCA to reduce and methylate Hg(II). The highest efficiency of 3.09%± 0.16% was achieved for bacterial Hg-methylation upon exposure to 10 μg/L Hg(II). Metabolomics data showed that carbohydrate metabolism, amino acid metabolism and nucleotide metabolism were disturbed by Hg(II) stress in the PCA cells. To withstand the stress of Hg(II), G. sulfurreducens PCA increased energy demand for Hg methylation and DNA repair. 
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Microbial Structure and Function of Activated Sludge in Landfill Leachate Treatment Plant
ZHANG Xue, QIAO Xuejiao, SU Jia, ZHANG Liyu, YU Ke
Acta Scientiarum Naturalium Universitatis Pekinensis    2021, 57 (5): 927-937.   DOI: 10.13209/j.0479-8023.2021.069
Abstract739)   HTML    PDF(pc) (3082KB)(203)       Save
16S rRNA gene and metagenomic sequencing was applied to study the structure of microbial community, functional microorganisms and genes in activated sludge of landfill leachate treatment. The results showed that Calditrichaeota was the most abundant phylum (58.77%), followed by Proteobacteria (16.80%) and Bacteroides (6.19%). Calrithrix was the dominant genus of the activated sludge (58.77%). Five nitrogen cycle pathways were detected to form the microbial community of activated sludge, including nitrification, denitrification, assimilation nitrate reduction, dissimilation nitrate reduction and nitrogen fixation. Denitrification genes were the most abundant among nitrogen cycling process (78.84%), which mainly distributed in Calditrichaeota, Proteobacteria and Choroflexi. Nitrification was achieved by ammonia oxidizing bacteria Nitrosomonas. There were abundant organic pollutants degradation genes in activated sludge. Proteobacteria, Bacteroides, Planctomycetes, Calditrichaeota and Choroflexi were typical functional microorganisms that can degrade organic pollutants. 
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Removal of Two Quinolone Antibiotics from Aqueous Solution by the Municipal Sewage Sludge-Based Adsorbent
TAO Huchun, GONG Yiwei, ZHANG Lijuan, DING Lingyun, ZHANG Shanfa
Acta Scientiarum Naturalium Universitatis Pekinensis    2021, 57 (4): 765-772.   DOI: 10.13209/j.0479-8023.2021.060
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The municipal sewage sludge was used as an raw material to prepare the sewage sludge-based adsorbent (SSA) by HNO3 activation, NaOH activation and H2O2 oxidation modification. The removal of ciprofloxacin (CIP) and lomefloxacin (LOM) from aqueous solution and the influencing factors were studied. Scanning electron microscopy and Fourier transform infrared spectroscopy were used to characterize the microstructure and functional groups on the surface of SSA. The effects of adsorbent dosage, temperature, the initial pH of solution, the ionic strength and other factors on the removal of CIP and LOM by SSA were investigated. The results showed that the modified SSA activated by 0.1 M HNO3 was most effective for removal of CIP and LOM. The rough structure of the modified adsorbent could provide more sites for antibiotic adsorption, and the oxygen-containing functional groups were able to form hydrogen bonds to enhance the adsorption of organic matters in solution. When the antibiotic concentration was 10 mg/L, the adsorption capacity of CIP and LOM was 8.95 and 7.28 mg/g, and removal rates were 90% and 73%, respectively. The adsorption process of CIP and LOM on the modified SSA was in accordance with the pseudo-second-order model, and Langmuir isotherm equation could well describe the adsorption behavior of CIP and LON on the modified SSA, which proved that adsorption process was monolayer chemisorption. The adsorbent removed 84% CIP and 67% LOM after 5 cycles, thus providing an efficient and sustainable way of antibiotic removal. 
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Growth Conditions of a Hydrogen-Oxidizing Bacterium and Its Utilization of Different Nitrogen Sources
TAO Huchun, XIE Yong, ZHANG Lijuan, DING Lingyun, CHEN Yizhen
Acta Scientiarum Naturalium Universitatis Pekinensis    2021, 57 (4): 756-764.   DOI: 10.13209/j.0479-8023.2021.059
Abstract732)   HTML    PDF(pc) (3612KB)(95)       Save
An autotrophic hydrogen-oxidizing bacterium, named Rhodoblastus sp. TH20, was successfully enriched and isolated from municipal activated sludge in a domestic wastewater treatment plant. With simulated ammonium-containing wastewater as culture medium, the strain could utilize H2 and CO2 as energy and carbon sources respectively and the growth conditions were optimized at 25℃, 160 rpm and pH=7.0. At initial concentration of 100 mg/L, efficient ammonium removal (>99%) was achieved within 72 hours. Up to 77.8% of ammonium was assimilated to organic nitrogen and stored intracellularly, while the rest ammonium was transformed to gaseous N2. These results indicated that Rhodoblastus sp. TH20 was able to efficiently convert ammonium into microbial protein, thereby providing a sustainable pathway of wastewater treatment. 
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Photocatalytic Degradation of Ciprofloxacin by Magnetic CoFe2O4/g-C3N4 Nanocomposites
TAO Huchun, DENG Liping, ZHANG Lijuan, DING Lingyun
Acta Scientiarum Naturalium Universitatis Pekinensis    2021, 57 (3): 587-594.   DOI: 10.13209/j.0479-8023.2021.037
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Magnetic CoFe2O4/g-C3N4 nanocomposites were synthesized and its surface morphology, element and chemical composition, specific surface area, functional group characteristics and crystal structure were characterized. Targeting at quinolone antibiotics of ciprofloxacin (CIP), the photo-catalytic degradation of CIP by CoFe2O4/g-C3N4 nanocomposites was investigated at different calcination temperature (300oC, 400oC and 500oC) and composite ratio (CoFe2O4:g-C3N4=10%, 20% and 40%, w/w). Under optimal synthesis and operating conditions, a maximum degradation efficiency of 75.1 ± 0.1% was achieved for 0.9 g/L CoFe2O4/g-C3N4 with 10 mg/L CIP (pH=6.6) within 120 min. With an external magnetic field, the CoFe2O4/g-C3N4 nanocomposites were easily and rapidly recycled, remaining >90% of the initial efficacy after 5 cycles and showing a considerable stability. Fluorescence spectra revealed a significant decrease in electron-hole recombination rates under light radiation, which contributed greatly to the increase of photo-degradation efficacy of CIP by CoFe2O4/g-C3Nnanocomposites.
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Influence of Propionate on Performance and Community Structure of an Anammox Reactor
ZHANG Liyu, QIAO Xuejiao, YU Ke
Acta Scientiarum Naturalium Universitatis Pekinensis    2021, 57 (3): 545-555.   DOI: 10.13209/j.0479-8023.2021.031
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In order to study the long-term influence of organic carbon on performance and community structure of an Anammox reactor, propionate was amended stepwise into an enriched Anammox reactor to investigate the dynamic change of the structure and function of the community. The results suggested that nitrogen removal process was mainly achieved by Candidatus Brocadia. Carbon and nitrogen were simultaneously removed by the growth of heterotrophic bacteria under 100 mg/L propionate, while total nitrogen removal efficiency reached 91.9%. A suppression of growth of Candidatus Brocadia and a significant reduction of total nitrogen removal were observed at the present of 200 mg/L propionate. The relative abundance of Candidatus Brocadia and total nitrogen removal efficiency decreased to 41.2% and 78.8% respectively. After propionate concentration recovered to 0 mg/L, the nitrogen removal efficiency of the reactor improved to 86.8% and the abundance of Candidatus Brocadia was recovered to 54.0%. However, the community diversity decreased and the microbial composition at genus level changed a lot.
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CMIP5 Climate Multi-model Ensemble Optimization Based on Spatial-Temporal Distribution
ZUO Zhengkang, ZHANG Feizhou, ZHANG Ling, SUN Yiyuan, ZHANG Ruihua, YU Tian, LU Jianzhong
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (5): 805-814.   DOI: 10.13209/j.0479-8023.2020.057
Abstract970)   HTML    PDF(pc) (7751KB)(233)       Save
The multi-mode ensemble based on spatiotemporal distribution is constructed to reduce the uncertainty of a single-model and the non-uniform distribution of the traditional model ensembles. The improved genetic algorithm is employed to optimize the multi-model ensemble of CMIP5 global climate data from temporal and spatial scales, and Taylor diagram is used to evaluate its simulation performance. The experimental results show that the multi-mode ensemble based on spatiotemporal distribution is superior to the traditional equal weight multimode ensemble scheme.
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Study on the Catalytic Oxidation of Rhodamine B by Nanoporous Carbon Materials Loaded with Zero Valence Copper
WANG Aide, FENG Zhendong, QIN Dayu, ZHANG Lijuan, ZHU Lili, ZHANG Shanfa, TAO Huchun
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (4): 703-709.   DOI: 10.13209/j.0479-8023.2020.033
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Nanoporous carbon material loaded with zero-valent copper NPC@Cu was synthesized by one-step carbonization method using copper-based MOF (HKUST-1, [Cu3(BTC)2], BTC as 1,3,5-benzenetricarboxylic acid) as template. With NPC@Cu as catalyst, peroxymonosulfatesulfate (PMS) was activated as oxidant to treat simulated azo dye wastewater by heterogeneous catalytic oxidation at ambient pressure and room temperature. The catalysts were characterized by electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), etc. The effect of degradation efficiency of the catalyst dosage, oxidant dosage and initial pH during the reaction were studied. The experimental results showed that the degradation rate of 0.10 mmol/L RhB can reach 100% after 45 minutes of reaction at a catalyst dosage of 0.1 g/L, a PMS concentration of 2.00 mmol/L and a initial pH of 7. Through the free radical trapping experiment, it proved that there are two free radicals in the system—SO4·and ·OH, and NPC@Cu is a catalytic material with good catalytic performance.
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Preparation of Magnetic g-C3N4-Fe3O4 Nanocomposites and the Photocatalytic Degradation of Three Quinolones in Aqueous Solution
TAO Huchun, LIANG Hongfei, ZHANG Lijuan, DING Lingyun, ZHANG Shanfa, ZHU Lili, DENG Liping
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (3): 546-552.   DOI: 10.13209/j.0479-8023.2020.026
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Magnetic g-C3N4-Fe3O4 nanomaterials were prepared by using melamine and iron salts as raw materials, and the effects of different operating factors on the photocatalytic degradation of three quinolone antibiotics were investigated. The optimal conditions for the photocatalytic reactions were: initial antibiotic concentration of 3.0 mg/L, initial g-C3N4-Fe3O4 dose of 0.60 g/L, at 25℃, and pH=7. Under optimized conditions, the degradation efficiencies of Lomefloxacin, Ofloxacin and Ciprofloxacin were 83.6%, 60.9% and 99.0% after 100 min light irradiation, respectively. XRD and UV-vis analyses show that the graphite-phase g-C3N4 has strong interaction with magnetic Fe3O4, resulting in the formation of more photogenerated electron-hole pairs and enhancing the photocatalytic activity of the composite nanomaterials. After repeated recycling for 5 times, there are more than 90% of magnetic g-C3N4-Fe3O4 nanomaterials recovered, and the photocatalytic efficiency is maintained at higher than 60%.
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Study on the Effect of Two Red-Tide Algae on Mercury Biocondensation and Methylation
TAO Huchun, YANG Sai, DING Lingyun, ZHANG Lijuan, HE Ningning, ZHANG Yaoyu
Acta Scientiarum Naturalium Universitatis Pekinensis    2019, 55 (4): 709-716.   DOI: 10.13209/j.0479-8023.2019.047
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The effect of two red-tide algae of Alexandrium tamarens and Scrippsiella trochoidea on mercury (Hg) adsorption and methylation were investigated. The inhibitory effect of two algae on biomethylation of Geobacter Sulfurreducens (G. sulfurreducens) PCA were demonstrated. The growth of Scrippsiella trochoidea was inhibited under exposure to high concentration of HgCl2 (≥25 μg/L), but less affecting Alexandrium tamarens. Significant adsorption of Hg2+ was observed onto algal cells, whilst negligible amount of methylmercury (MeHg) was produced by two algae directly. FTIR spectra revealed that hydroxyl, carboxyl and amino groups were major binding sites for Hg2+ adsorption. In Hg-algae-bacteria tests, at initial HgCl2 concentration of 10 μg/L, a maximum mercury methylation efficiency of (6.38±0.4)% was obtained by pure G. sulfurreducens PCA culture as a control, but the efficiency reduced to (1.04±0.44)% with G. sulfurreducens PCA and Alexandrium tamarens coexisting, and a much lower efficiency of (0.76±0.05)% was detected with G. sulfurreducens PCA and Scrippsiella trochoidea coexisting. These results suggested that two red-tide algae inhibited mercury biomethylation of G. sulfurreducens PCA.
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Thio-Aminopropyltriethoxysilane-Modified Porous Glass-Ceramics as New Sorbents for Palladium (II) Separation from Wastewater
TAO Huchun, HUANG Shuaibin, GU Yihan, ZHANG Lijuan, ZHU Lili
Acta Scientiarum Naturalium Universitatis Pekinensis    2019, 55 (2): 360-366.   DOI: 10.13209/j.0479-8023.2018.100
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Thio-aminopropyltriethoxysilane-modified porous glass-ceramics (TAMPG) were prepared through reuse of waste glass for efficient palladium (II) separation from wastewater. Novel TAMPG-1, TAMPG-2, TAMPG-3 were obtained by immobilizing organic ligands 2-thiophene formaldehyde, 2-mercaptobenzimidazoles and 2-mercaptobenzothiazole onto the surface of porous glass-ceramics made from waste glass. Optimal conditions for effective palladium (II) adsorption were investigated with respect to pH, temperature, initial concentration and contact time. Owing to cheap raw materials, good adsorption properties, great recycling potential, excellent selectivity and stability, an economically viable method was proposed for efficient palladium (II) separation from wastewater.

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Preparation and Optimization of a Novel Magnetic Chitosan/Sodium Alginate Composite Gel Bead
TAO Huchun, LI Shuo, ZHANG Lijuan, LI Jinbo, YANG Sai
Acta Scientiarum Naturalium Universitatis Pekinensis    2018, 54 (4): 899-906.   DOI: 10.13209/j.0479-8023.2017.186
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Using sodium alginate hydrogel as skeleton, in combination with chitosan and magnetic Fe3O4, a new type of magnetic chitosan/sodium alginate gel bead was prepared. On this basis, through the orthogonal experiment and single-factor experiment, the authors optimized the preparation conditions for composite gel bead, and determined the optimum one. The influences of many preparation impact factors on adsorption performance were examined. Results show that the optimal preparation conditions for the composite gel bead is as follows. Concentration of calcium chloride is 2.5 g/L, concentration of sodium alginate is 24 g/L, the amount of chitosan addition is 5 g/L, and the amount of magnetic liquid addition is 4.64 g/L. The optimal gel bead is a smooth, uniform, black ball with about 2 mm in diameter. By Fourier transform infrared spectroscopy (FTIR), synchronous thermal analysis (TGA) and other means of characterization, the adsorption mechanism is analyzed. Thermogravimetric analysis results show that the gel bead has good thermal stability. FTIR results prove that many active functional groups (amino group, hydroxyl group and carboxyl group) exist on the surface of gel bead. The adsorption performance test shows that adsorption ratio of 20mg MCSB on 40mL 25mg/L Cu2+ solution is 78.13%. The magnetic chitosan/sodium alginate gel bead is a novel simple-prepared and effective composite adsorbent.

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Removal Features of DOM in Bio-Treated Effluents by Enhanced Coagulation Process
WANG Jingbo, ZHANG Linnan, LI Zhenshan
Acta Scientiarum Naturalium Universitatis Pekinensis    2018, 54 (3): 633-643.   DOI: 10.13209/j.0479-8023.2017.175
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Three advanced flocculants were used to treat the biochemical treatment samples extracted from the landfill leachate. In order to explore the transformation characteristics of dissolved organic matter (DOM) in the process of coagulation, all the samples’ DOM from three stages were characterized by ultraviolet-visible spectra (UV-Vis), three dimensional fluorescence spectra (EEM) and Fourier transform ion cyclotron resonance electrospray mass spectrometry (ESI FT-ICR MS). UV-Vis spectra showed that the ratio of small molecules increased in water while both the humification degree and condensation degree reduced after coagulation. EEM suggested that the removal efficiency of protein and humic acid substances were very high after coagulation. FT-ICR MS indicated that there was a strong selectivity of flocculants for the removable DOM in different stages of coagulation. DOM in the final residual water was mainly smaller molecular weight, containing impurity atoms with low unsaturation, O/C<0.3, and H/C>1.5.

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Petroleum Geology and Exploration Potential of Vienna Basin
ZHANG Hongwei, LI Jianghai, ZHANG Liwei
Acta Scientiarum Naturalium Universitatis Pekinensis    2016, 52 (5): 881-890.   DOI: 10.13209/j.0479-8023.2016.047
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The oil geology feature of Vienna Basin was summarized and potential of exploration was discussed by analysising the strata of Vienna Basin and fracture development characteristics. Vienna Basin is a pull-apart basin located between the East Alps and West Carpathian. Its basement is composed of the Hercynian Bohemian Massif and Paleozoic and Mesozoic strata. The tectonic evolution can be divided into three stages, including Jurassic extensional rifting, Cretaceous-Early Miocene over-thrusting and Middle Miocene pull-parting stage. There are three structural lays from top to bottom, Jurassic-Cretaceous autochthonous, Permian-Paleogene allochthonous Alpine nappes and Neogene sediments. There are two sets of source rocks: the upper Jurassic marls and Paleogene shale, among which, the Upper Jurassic Kimmeridgian Malmian marls are considered to be the major source rocks. Reservoirs occur at various horizons from Triassic to Neogene Miocene strata, among which, the most important reservoirs are Miocene sandstones that deposit in shallow-water delta environment and contain 76% of all reserves, and the minor reservoirs are the Triassic dolosparite. Neogene shales provide the regional top-seal. After evaluation, it is considered that Mesozoic allochthonous napps (flysch turbidite and Triassic dolomite) and Mesozoic autochthonous succession (the second and the third structural layer) are the most prospective for exploration.

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Development and Trend Analysis of Wastewater Resource Recovery Research Based on Bibliometrics Methods and Data during the Period 1995–2014
ZHANG Li, LIU Yangsheng
Acta Scientiarum Naturalium Universitatis Pekinensis    2016, 52 (2): 374-382.   DOI: 10.13209/j.0479-8023.2015.152
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 For better understanding the global trend in wastewater resource recovery and reflecting major nation’s scientific capability and influences on the world’s science community in the field, a bibliometric analysis was conducted using the literatures in the Science Citation Index (SCI) database during the period 1995–2014. Results indicate that: 1) among all articles included by the SCI, water recovery from wastewaters account for the largest percentage with 72.0% of all related research fields. 2) The mainly involved subject areas are Environmental Sciences, Engineering Environmental, Water Resources, Engineering Chemical, Biotechnology Applied Microbiology, and so on. The number of the Environmental Sciences articles has the largest annual growth. 3) The topranked countries of both the total number of articles and the average impact factor are USA, Spain, and India. However, China has the fastest growth rate of publishing articles only. 4) Three research institute including University of California System, India Institute of Technology, and Consejo Superior De Investigaciones Cientificas are the most abundant research institutes in this field. The Chinese Academy of Sciences and Tsinghua University were the two toppest institutions in China that have advance its international influence in recent years.

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Microclimate Effects of Campus Green Space in Summer
FENG Yueyi,LI Enjing,ZHANG Lixiao
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract980)      PDF(pc) (1505KB)(617)       Save
Four representative types of green space including tree-shrub-herbage semi-natural mixture, tree-shrub-herbage artificial mixture, tree-herbage artificial mixture, and artificial lawn were selected in the campus of Peking University to study the improvement effects of green space on campus microclimate, especially on the human comfort. The air temperature and relative humidity were measured every one hour from 0:00 to 24:00 every day for continuously 32 days during July and August in 2012. The results indicate that all types of green space show significant cooling and humidification effects compared with the concrete floor in hot summer. Among these, the semi-natural forests perform a very important ecological regulatory function. During the observation period, all types of green space improve the human comfort degree to a certain extent, which are ranked in an order of tree-shrub-herbage semi-natural mixture > tree-herbage artificial mixture > tree-shrub-herbage artificial mixture > artificial lawn, but the improvement effect is not as obvious as their cooling and humidification effects. From the perspective of the different times of a day, the comfort improvement of the green space is more obvious early in the morning and late in the evening than that at any other time of a day. As a whole, some parts of the green space in the campus of Peking University don’t give full play to the improvement effects of the campus comfort according to the various functional requirements in summer, which deserves further attention in the campus green space construction.
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Theoretical Model of Non-linear ICP Co-registration Based on Fast Approximation of 1st Polynomials Extension
ZUO Zhiquan,LIU Zhengjun,ZHANG Li
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract1092)      PDF(pc) (1758KB)(643)       Save
In order to avoid the drawback of the traditional ICP (iteration closest point) method for co-registration, a non-linear least squares co-registration model is proposed, which is based on minimizing the sum of squares of the Euclidean distances between two overlapped surfaces. The experiments demonstrate that the proposed method can be used for the co-registration of cloud points collected by the airborne laser scanner, and the experimental results are comparable with those of traditional methods. The experimental results imply that the proposed method has a good performance for transformation parameters estimation in 3D point clouds co-registration procedure. Especially, the non-linear co-registration method can achieve the best estimated value with only 6 to 7 iteration time. It is much faster than traditional method in practice, and can be treated as an extension for traditional co-registration theory of iteration closest point in the field of computer vision.
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A Fast Watermarking Algorithm with Low Complexity Error Compensation in H.264/AVC Bit-Stream
ZHANG Liwei,ZHU Yuesheng,Po Lai-man
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract716)      PDF(pc) (1684KB)(348)       Save
Watermarking algorithms in the H.264/AVC bit-stream are more efficient, but the propagation error introduced would decrease the visual quality severely. In order to reduce the computation complexity of compensation, a new error compensation method is proposed, in which the watermark is embedded into the quantized DCT coefficients and the propagation error gained by a low complexity error prediction module are compensated adaptively. The simulation results show that with the proposed compensation method, a real time video watermarking can be realized, with the features of low complexity, high PSNR and less bitrate increase.
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Identification and Application of Seasonality Parameters of Crop Growing Season in Northeast China Based on NDVI Time Series Data
LI Zhengguo,TANG Huajun,YANG Peng,ZHOU Qingbo,WANG Yanglin,WU Wengbin,YIN He,ZHANG Li
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract698)      PDF(pc) (3348KB)(556)       Save
The authors investigated spatio-temporal patterns of seasonality parameters of crop growing season in Northeast China, by using the SPOT/VGT NDVI ten day composed time-series data collected from 1998 to 2009. First, to minimize the effects of anomalous values caused by atmospheric haze and cloud contamination, the software TIMESAT was used to generate smooth time series of NDVI based on an asymmetric Gaussian function; second, the seasonality parameters, such as the start date, the end date, the peak date, and length of the growing season, were defined and extracted from the smoothed NVDI time-series dataset; third, each of the extracted parameters and the observed agricultural phenophases (including the stages of seedling, heading and maturity for harvest, length of growth period) were compared and validated by using a scatter plot, respectively; finally, the temporal trends and spatial patterns of the major crop seasonality parameters in Northeast China were illustrated and analyzed over the past 10 years. The results show that the growth process of major crops can be discriminated to a certain extent from the temporal trend of observed crop phenological characteristics. Obvious linear correlations can be found between the extracted seasonality parameters and the observed crop phenophases, which indicates that spatio-temporal variations of crop phenophase can be expressed in details by utilizing the extracted parameters from the smoothed NDVI time series. Meanwhile, all these grid-based crop phenophases can be used as data alternative for studying the spatio-temporal responses of crop growth process caused from fluctuation in external environmental conditions, such as air temperature, precipitation and daylight hours, etc.
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Studies of Photoluminescence and Microcavity Properties of One-Dimensional CdS Nanostructures
YAN Guoqing,LI Dan,ZHANG Lihuan,ZHAO Bowen,FU Xiuli,GAO Min
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract557)            Save
The authors perform combined temperature dependent macro-photoluminescence (PL) and confocal spatially resolved PL measurements to study the luminescence mechanism and the microcavity properties of one-dimensional CdS nanostructures (nanobelts and nanorods) grown by catalyst-assisted chemical vapor deposition. The dependence of the PL on the temperature (10-290 K) indicates clearly that the room temperature near band edge (NBE) emission mainly consists of excitonic emission and its phonon replicas. Both the end facets and the sidewalls of individual nanostructures may exhibit strong confinement on the NBE emission, leading to Fabry-Perot (FP) and whispering gallery (WG) cavities with pronounced nonlinear characteristics. The deep level defect emission forms strong cavity modes with equal spacings in WG cavities, but experiences large damping along the nanostructure axes in FP cavities. The results are helpful in understanding the mechanisms of the nanostructure optical microcavities, and support the exciton-polariton model of the exciton-related cavity modes.
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Research on Phosphorus Removal from Wastewater by TBX Porous Ceramisite Filter Media
LIU Baohe,ZHANG Linsheng,MENG Guanhua,ZHENG Jun
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract704)            Save
To provide the slight alkaline environment and sufficient calciumions is the important condition to achieve efficient adsorption phosphate by adsorbent. Taking cement, xonotlite, clay, flying ash and CaO as primary raw materials, TBX porous ceramisite filter media was prepared by hydrothermal reaction and steam curing. Based on the leaching rate of calcium ions and pH transients of lixivium, the operation conditions were achieved. The filter media was applied to remove the low concentration phosphate in wastewater. The results show that under the dose of filter media 1% (mass fraction) and 10 mg/L of phosphate, after 120 min of adsorption, the concentration of residual phosphate could be reduced to 0.2mg/ L which was far lower than the State-specified standards. As the result of the properties of efficient phosphate adsorption and low cost, TBX porous ceramisite filter media should be promising in the field of the treatment of severe-eutrophic water body and municipal sewage.
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Non-perturbative SpectrumCalculation of Vortex Solid in Type-ⅡSuperconductors
ZHANG Li,CHEN Shuo,CHEN Yu,LI Dingping
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract811)            Save
The excitations in lattice in type-Ⅱsuperconductors in magnetic field contain acoustic and optical phonons. The acoustic phonon is Goldstone Boson with zero mass. By using Gaussian variational method, the authors calculate dispersion relations of acoustic and optical phonons non-perturbatively based on Ginzburg-Landau model with lowest Landau level approxi mation.
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Autobiographical Memories of Shame: A Comparative Study in the Context of Cultural Differences of Self
ZHANG Zhifeng,GAOJun,QIAN Mingyi,WANG Aimin,ZHANG Lili,WANG Zhiyan
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract729)            Save
The main objective was to comparethe emotion of shame under Chinese culture and American culture, based on the self theory of Markus and Kitayama. There were 69 Chinese collage students and 65 American collage students involved in this study. Each subject was asked to recall one shameful event he or she experienced. Then based on the theoretical hypothesis and characters of these shameful autobiographical memories, a coding scheme was developed. All autobiographical memories were coded according to the scheme. The main results are as follows: 1) the shameful autobiographical memories of Chinese subjects were more specific than those of the American subjects’; 2) compared with those of the American subjects, Chinese subjects’autobiographical memories contained more interpersonal contents; and 3) compared with the American subjects, Chinese subjects reported more shameful autobiographical memories happened in the period of childhood and adolescence, in the places of school and with teachers’comments on the events.
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Logging Response to the Volcanic Cycles of the First Member of Yingcheng Formation in Xujiaweizi Fault Depression
ZHANG Liwei,SHI Yongmin,LI Jianghai
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract524)            Save
The volcanic rocks of the Yingcheng formation in the Songliao Basin were formed by multiple and intermittent eruptions. Based on the core drilling data, the high-resolution volcanic cycles of the first member of Yingcheng formation in Xujiaweizi fault depression were divided, the volcanic cycle model were built, and the well logging characteristics of different lithology and lithofacies were summarized. The results reveal that, the first member of Yingcheng formation could be divided into 3 volcanic cycles, from the top to the bottom of each cycle, the values of gamma-ray and resistivity were higher and higher, the amplitude and frequency of the well logs in the interface of different cycles changed greatly, indicating the existence of the weathering crust or the sedimentary layer. Logging data of gamma-ray, resistivity and density were considered to be more sensitive in recognition of different volcanic lithology and lithofacies.
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Mg-Carpholite Metapelite and Its Implications for Ancient Oceanic Subduction in the North Qilian Suture Zone, NW China
YU Xiaoning,SONG Shuguang,WEI Chunjing,ZHANG Lifei
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract735)            Save
A typical Early Paleozoic oceanic suture zone, which consists of ophiolite, arc volcanic rocks and high-pressure low-temperature metamorphic rocks, occurs in the North Qilian Mountains, Northwestern China. Eclogite facies metapelites with index mineral assemblage of Mg-carpholite + garnet + chloritoid + phengite were studied in details in petrology and mineralogy. Using THERMORCAL (V3.23), the authors calculated the P-T conditions of the stability field for Carpholite (cr) + garnet (g) + chloritoid (ct) + phengite (ph) assemblage at P=2.2-2.5GPa and T=530-580℃. Based on the calculated stability fields of carpholite and chloritoid, the authors confirmed that the North Qilian suture zone was a “cold" oceanic subduction zone in Early Paleozoic time with geothermal gradients of 6.5-7.5℃/km, similar to Mesozoic-Cenozoic subduction zones. This study plays an important role in understanding the thermo-structure of the Early Paleozoic subduction zones and dehydration of HP metamorphic pelitic rocks.
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