Thio-aminopropyltriethoxysilane-modified porous glass-ceramics (TAMPG) were prepared through reuse of waste glass for efficient palladium (II) separation from wastewater. Novel TAMPG-1, TAMPG-2, TAMPG-3 were obtained by immobilizing organic ligands 2-thiophene formaldehyde, 2-mercaptobenzimidazoles and 2-mercaptobenzothiazole onto the surface of porous glass-ceramics made from waste glass. Optimal conditions for effective palladium (II) adsorption were investigated with respect to pH, temperature, initial concentration and contact time. Owing to cheap raw materials, good adsorption properties, great recycling potential, excellent selectivity and stability, an economically viable method was proposed for efficient palladium (II) separation from wastewater.
Using sodium alginate hydrogel as skeleton, in combination with chitosan and magnetic Fe3O4, a new type of magnetic chitosan/sodium alginate gel bead was prepared. On this basis, through the orthogonal experiment and single-factor experiment, the authors optimized the preparation conditions for composite gel bead, and determined the optimum one. The influences of many preparation impact factors on adsorption performance were examined. Results show that the optimal preparation conditions for the composite gel bead is as follows. Concentration of calcium chloride is 2.5 g/L, concentration of sodium alginate is 24 g/L, the amount of chitosan addition is 5 g/L, and the amount of magnetic liquid addition is 4.64 g/L. The optimal gel bead is a smooth, uniform, black ball with about 2 mm in diameter. By Fourier transform infrared spectroscopy (FTIR), synchronous thermal analysis (TGA) and other means of characterization, the adsorption mechanism is analyzed. Thermogravimetric analysis results show that the gel bead has good thermal stability. FTIR results prove that many active functional groups (amino group, hydroxyl group and carboxyl group) exist on the surface of gel bead. The adsorption performance test shows that adsorption ratio of 20mg MCSB on 40mL 25mg/L Cu2+ solution is 78.13%. The magnetic chitosan/sodium alginate gel bead is a novel simple-prepared and effective composite adsorbent.
Three advanced flocculants were used to treat the biochemical treatment samples extracted from the landfill leachate. In order to explore the transformation characteristics of dissolved organic matter (DOM) in the process of coagulation, all the samples’ DOM from three stages were characterized by ultraviolet-visible spectra (UV-Vis), three dimensional fluorescence spectra (EEM) and Fourier transform ion cyclotron resonance electrospray mass spectrometry (ESI FT-ICR MS). UV-Vis spectra showed that the ratio of small molecules increased in water while both the humification degree and condensation degree reduced after coagulation. EEM suggested that the removal efficiency of protein and humic acid substances were very high after coagulation. FT-ICR MS indicated that there was a strong selectivity of flocculants for the removable DOM in different stages of coagulation. DOM in the final residual water was mainly smaller molecular weight, containing impurity atoms with low unsaturation, O/C<0.3, and H/C>1.5.
The oil geology feature of Vienna Basin was summarized and potential of exploration was discussed by analysising the strata of Vienna Basin and fracture development characteristics. Vienna Basin is a pull-apart basin located between the East Alps and West Carpathian. Its basement is composed of the Hercynian Bohemian Massif and Paleozoic and Mesozoic strata. The tectonic evolution can be divided into three stages, including Jurassic extensional rifting, Cretaceous-Early Miocene over-thrusting and Middle Miocene pull-parting stage. There are three structural lays from top to bottom, Jurassic-Cretaceous autochthonous, Permian-Paleogene allochthonous Alpine nappes and Neogene sediments. There are two sets of source rocks: the upper Jurassic marls and Paleogene shale, among which, the Upper Jurassic Kimmeridgian Malmian marls are considered to be the major source rocks. Reservoirs occur at various horizons from Triassic to Neogene Miocene strata, among which, the most important reservoirs are Miocene sandstones that deposit in shallow-water delta environment and contain 76% of all reserves, and the minor reservoirs are the Triassic dolosparite. Neogene shales provide the regional top-seal. After evaluation, it is considered that Mesozoic allochthonous napps (flysch turbidite and Triassic dolomite) and Mesozoic autochthonous succession (the second and the third structural layer) are the most prospective for exploration.
For better understanding the global trend in wastewater resource recovery and reflecting major nation’s scientific capability and influences on the world’s science community in the field, a bibliometric analysis was conducted using the literatures in the Science Citation Index (SCI) database during the period 1995–2014. Results indicate that: 1) among all articles included by the SCI, water recovery from wastewaters account for the largest percentage with 72.0% of all related research fields. 2) The mainly involved subject areas are Environmental Sciences, Engineering Environmental, Water Resources, Engineering Chemical, Biotechnology Applied Microbiology, and so on. The number of the Environmental Sciences articles has the largest annual growth. 3) The topranked countries of both the total number of articles and the average impact factor are USA, Spain, and India. However, China has the fastest growth rate of publishing articles only. 4) Three research institute including University of California System, India Institute of Technology, and Consejo Superior De Investigaciones Cientificas are the most abundant research institutes in this field. The Chinese Academy of Sciences and Tsinghua University were the two toppest institutions in China that have advance its international influence in recent years.